BODIPY-Br熒光小分子的結(jié)構(gòu)式

氟硼二吡咯(BODIPY)熒光染料具有其摩爾消光系數(shù)大,熒光量子產(chǎn)率高,光物理化學(xué)以及易于進(jìn)行化學(xué)改性等優(yōu)點(diǎn)。西安齊岳生物實(shí)驗(yàn)室供應(yīng)熒光小分子BODIPY-Br

隨著新時(shí)期高分子材料在生物和醫(yī)學(xué)領(lǐng)域的迅速發(fā)展,多元化的材料越來越受到人們的需求,環(huán)境響應(yīng)的兩親性聚合物可以作為科研的載體,用于運(yùn)輸,釋放等領(lǐng)域;結(jié)合氟硼二吡咯熒光分子光物理和光化學(xué)性質(zhì),設(shè)計(jì)合成具有響應(yīng)性的熒光高分子材料具有重要的意義.總結(jié)近研究成果和可控聚合反應(yīng)的發(fā)展,合成熒光分子引發(fā)劑和熒光分子單體,通過ATRP法合成了對p H和溫度響應(yīng)的兩親性嵌段共聚物,并對合成的聚合物進(jìn)行表征及自組裝形態(tài)進(jìn)行了探究。

1.選擇以對羥基與2-溴異丁基酰溴發(fā)生酯化反應(yīng),再與2,4-二甲基吡咯結(jié)合制備熒光分子引發(fā)劑BODIPY-Br,通過原子轉(zhuǎn)移自由基聚合(ATRP,Atom Transfer Radical Polymerization)合成大分子引發(fā)劑聚苯乙烯[BODIPY-PS-Br].以甲基丙烯酸二乙氨基乙酯(DEAEMA)為單體,BODIPY-PS-Br為引發(fā)劑CuBr/PMDETA(N,N,N',N,'N''-五甲基二亞乙基三胺)為催化體系,ATRP法合成嵌段共聚物聚苯乙烯-b-聚甲基丙烯酸二乙氨基乙酯[BODIPY-PS-b-DEAE MA].并通過調(diào)整投入單體的量不同,合成不同鏈長的聚合物BODIPY-PS-b-DEAEMA樣品.

西安齊岳生物提供有機(jī)發(fā)光材料(聚集誘導(dǎo)發(fā)光材料AIE材料)和發(fā)光探針(磷脂探針和酶探針)、熒光染料Cy3、Cy5、Cy7、ICG染料、碳量子點(diǎn)、苯并吡喃嗡類染料探針定制、金屬納米簇、氧雜蒽類染料、嵌段共聚物等一系列產(chǎn)品。也提供熒光染料標(biāo)記的蛋白,氨基酸,凝集素,多肽,藥,糖化學(xué),微球,離子液體等產(chǎn)品定制合成

BDP 558/568 NHS ester

BDP 564/570 NHS ester150173-90-3

BDP 576/589 NHS ester201998-61-0

BDP 581/591 NHS ester654651-21-5

BDP 630/650 X NHS ester2213445-35-1; 380367-48-6

BDP 650/665 X NHS ester1616842-78-4

BDP FL NHS ester146616-66-2

BDP R6G NHS ester1443457-59-7

BDP TMR NHS ester485397-12-4

BDP TR NHS ester150152-65-1

BDP TR X NHS ester197306-80-2

BDP 558/568 azide

BDP 581/591 azide2183473-20-1

BDP 630/650 azide2183473-22-3

BDP FL azide1379771-95-5；

BDP R6G azide2183473-23-4

BDP TMR azide2183473-25-6; 2373346-19-9

BDP TR azide2183473-27-8

BDP 558/568 alkyne

BDP 581/591 alkyne2006345-34-0

BDP 630/650 alkyne2006345-38-4

BDP 650/665 alkyne2006345-40-8

BDP FL alkyne302795-84-2, 2006345-30-6

BDP R6G alkyne2006345-31-7

BDP TMR alkyne2006345-32-8

BDP TR alkyne2006345-35-1

BDP 581/591 maleimide2183473-29-0

BDP 630/650 maleimide2183473-31-4

BDP 650/665 maleimide

BDP FL maleimide773859-49-7

BDP R6G maleimide2183473-32-5

BDP TMR maleimide2183473-34-7

BDP TR maleimide2183473-37-0

BDP 558/568 hydrazide

BDP 581/591 hydrazide2183473-40-5

BDP 630/650 hydrazide2183473-43-8

BDP FL hydrazide2183473-45-0

BDP R6G hydrazide

BDP TR hydrazide2183473-49-4

BDP 558/568 carboxylic acid150173-72-1

BDP 564/570 carboxylic acid150173-89-0

BDP 581/591 carboxylic acid480999-04-0

BDP 630/650 carboxylic acid2183512-02-7

BDP FL carboxylic acid165599-63-3

BDP R6G carboxylic acid174881-57-3

BDP TMR carboxylic acid287384-28-5

BDP TR carboxylic acid150152-64-0

BDP 558/568 amine

BDP 581/591 amine2183472-97-9

BDP 630/650 amine2183473-00-7

BDP FL amine2183473-03-0

BDP R6G amine2183473-06-3 (hydrochloride), 2183473-05-2

BDP TMR amine2183473-08-5 (free base)

BDP TR amine2183473-18-7

BDP 576/589 tetrazine

BDP 581/591 tetrazine

BDP 630/650 tetrazine

BDP FL tetrazine2042193-77-9

BDP R6G tetrazine

BDP TR tetrazine

BDP 581/591 DBCO

BDP FL DBCO2360493-46-3

BDP R6G DBCO

BDP 493/503 lipid stain121207-31-6

BDP 505/515 lipid stain21658-70-8

BDP TR methyl ester, 5 mM in DMSO

BODIPY FL, STP Ester, Sodium Salt

溫馨提示：產(chǎn)品用于科研，不能用于人體實(shí)驗(yàn)。zhn2021.11.26